Instructions to add the Payment Methods to Facebook for Social Ads:
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Log in to Business Manager (https://business.facebook.
com/settings) and go to the left-hand side menu. -
Scroll down and select “billing and payment”.
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On the left-hand side, select “payment methods”
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Hit “Modify permissions” and set yourself as Finance Editor. (You might need to refresh the page after this step or skip this step if you don’t see it.).
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Select the Grey “add” button next to “Add business payment method” towards the top center. (This is the card you want Facebook to bill).
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Enter card information and click save